Perfluoroorganylxenonium(II) salts from reactions of XeF2 or [FXe][SbF6] with selected perfluorinated alk-1-yn-1-yl- and alk-1-en-1-yltrifluoroborate salts in aHF
| Autor: | Hermann-Josef Frohn, Vadim V. Bardin |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Organic Chemistry Inorganic chemistry Xenon difluoride Chemie chemistry.chemical_element Salt (chemistry) Nuclear magnetic resonance spectroscopy Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Fluorine Anhydrous Environmental Chemistry Physical and Theoretical Chemistry Xenonium |
| Zdroj: | Journal of Fluorine Chemistry. 138:28-33 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2012.03.014 |
| Popis: | Xenon difluoride reacted with alkynylborate salts, K[R F C CBF 3 ], in anhydrous HF (aHF) to give alkynylxenonium salts, [R F C CXe][BF 4 ] (R F = CF 3 , C 3 F 7 , (CF 3 ) 2 CF), in 50–55% yield. Both [FXe][SbF 6 ] and K[C 3 F 7 C CBF 3 ] formed the [C 3 F 7 C CXe] + salt in aHF. In the reaction of XeF 2 with the alkenylborate salt, K[CF 2 C(CF 3 )BF 3 ], the competitive hydrodeboration reaction (formation of CF 2 C(CF 3 )H in 85% yield) exceeded the xenodeboration reaction (formation of the xenonium salt [CF 2 C(CF 3 )Xe][BF 4 ] in 15% yield only). K[4-BF 3 C 5 F 4 N] did not react with XeF 2 in aHF, but underwent fluorine addition in the presence of AsF 5 . |
| Databáze: | OpenAIRE |
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