Autor: |
Denis V. Korchagin, Alexander V. Akimov, Vasili Miluykov, Yulia S. Ganushevich, Eugenii Ya. Misochko |
Rok vydání: |
2017 |
Předmět: |
|
Zdroj: |
Angewandte Chemie (International ed. in English). 56(27) |
ISSN: |
1521-3773 |
Popis: |
Low temperature UV-photolysis of mesitylphosphiranes under strong anaerobic conditions leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X-band EPR spectrum of triplet MesP and the derived zero-field splitting parameter D = 4.116 cm-1 differ significantly from those reported previously for this intermediate. New magnetic parameters of mesitylphosphinidene are discussed along with the results of DFT calculations. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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