Role of Co dopants on the structural, optical and magnetic properties of lead-free ferroelectric Na0.5Bi0.5TiO3 materials
| Autor: | Luong Huu Bac, L.T.H. Thanh, Nguyen Hoang Linh, T.V. Trung, N. B. Doan, Nguyen Quoc Dung, D. V. Thiet, N.C. Khang, Dang Duc Dung, Nguyen Ngoc Trung, Nguyen Van Duc |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Magnetic moment Dopant Condensed matter physics Band gap Materials Science (miscellaneous) 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Ferroelectricity 0104 chemical sciences Electronic Optical and Magnetic Materials Biomaterials Condensed Matter::Materials Science Ferromagnetism Condensed Matter::Superconductivity Distortion lcsh:TA401-492 Ceramics and Composites Diamagnetism lcsh:Materials of engineering and construction. Mechanics of materials Condensed Matter::Strongly Correlated Electrons 0210 nano-technology Electronic band structure |
| Zdroj: | Journal of Science: Advanced Materials and Devices, Vol 4, Iss 4, Pp 584-590 (2019) |
| ISSN: | 2468-2179 |
| Popis: | Co-doped Na0.5Bi0.5TiO3 materials were fabricated by a sol-gel technique. The structural distortion of Co-doped Na0.5Bi0.5TiO3 materials was due to the difference between the radii of Co dopants and Ti hosts. The optical band gap decreased from 3.11 to 1.83 eV because of the local state of the Co cation in the band structure. Room temperature ferromagnetism emerged as compensation of diamagnetic background and possibly intrinsic ferromagnetic signals. The magnetic moment was determined to be ∼0.64 μB/Co at 5 K. The origin of the room temperature ferromagnetism in the Co-doped Na0.5Bi0.5TiO3 materials was also investigated through the first-principles calculation method. Our study provides physical insights into the complex magnetic nature of transition metal-doped ferroelectric perovskites and contributes to the integration of multifunctional materials into smart electronic devices. Keywords: Lead-free ferroelectric, Multiferroics, Na0.5Bi0.5TiO3, Ferromagnetism, Sol-gel |
| Databáze: | OpenAIRE |
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