Stereochemical Geometries and Photoluminescence in Pseudo-Halido-Zinc(II) Complexes. Structural Comparison between the Corresponding Cadmium(II) Analogs
| Autor: | Ana Torvisco, Sushant P. Sahu, Febee R. Louka, Shelby F. Aaron, Franz A. Mautner, Amber R. Dugas, Roland Fischer, Salah S. Massoud, Nahed M.H. Salem |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Tris
dicyanamide 010405 organic chemistry Chemistry zinc chemistry.chemical_element Zinc 010402 general chemistry 01 natural sciences 0104 chemical sciences X-ray Trigonal bipyramidal molecular geometry Crystallography chemistry.chemical_compound Octahedron azide Amine gas treating Isoquinoline Luminescence isothiocyanate Dicyanamide luminescence emission Inorganic chemistry QD146-197 |
| Zdroj: | Inorganics, Vol 9, Iss 53, p 53 (2021) Inorganics Volume 9 Issue 7 |
| ISSN: | 2304-6740 |
| Popis: | Six pseudohalide zinc(II) containing a variety of N-donor auxiliary amines were structurally characterized. These include two mononuclear trigonal bipyramidal [Zn(NTB)(N3)]ClO4·½H2O (3) and [Zn(TPA)(NCS)]ClO4 (4), two distorted octahedral [Zn(1,8-damnph)2(dca)2] (5) and [Zn(8-amq)2(dca)2] (6a) as well as two 1D polymeric chains catena-[Zn(isq)2(μ1,5-dca)2] (7) and catena-[Zn(N,N-Me2en)2(μ1,5-dca)]dca (8), where NTB = tris(2-benzimidazolylmethyl)amine, TPA = tris(2-pyridylmethyl)amine, 1,8-damnph = 1,8-diaminonaphthalene, 8-amq = 8-amino-quinoline, isq = isoquinoline (isq) and N,N-Me2en = N,N-dimethylethylenediamine. In general, with the exception of 6 and 8, the complexes exhibited luminescence emission in MeOH associated with red shift of the emission maxima, and the strongest visible fluorescence peak was detected at 421 nm (λex = 330 nm) in the case of Complex 5. |
| Databáze: | OpenAIRE |
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