Rheological Characteristics of 2D Titanium Carbide (MXene) Dispersions: A Guide for Processing MXenes
| Autor: | Bilen Akuzum, Babak Anasori, Yury Gogotsi, E. Caglan Kumbur, Pavel Lelyukh, Kathleen Maleski, Nicolas J. Alvarez |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Fabrication Titanium carbide General Engineering General Physics and Astronomy 02 engineering and technology Nitride 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Viscoelasticity 0104 chemical sciences Carbide chemistry.chemical_compound Rheology Chemical engineering chemistry General Materials Science 0210 nano-technology MXenes Suspension (vehicle) |
| Zdroj: | ACS Nano. 12:2685-2694 |
| ISSN: | 1936-086X 1936-0851 |
| DOI: | 10.1021/acsnano.7b08889 |
| Popis: | Understanding the rheological properties of two-dimensional (2D) materials in suspension is critical for the development of various solution processing and manufacturing techniques. 2D carbides and nitrides (MXenes) constitute one of the largest families of 2D materials with >20 synthesized compositions and applications already ranging from energy storage to medicine to optoelectronics. However, in spite of a report on clay-like behavior, not much is known about their rheological response. In this study, rheological behavior of single- and multilayer Ti3C2Tx in aqueous dispersions was investigated. Viscous and viscoelastic properties of MXene dispersions were studied over a variety of concentrations from colloidal dispersions to high loading slurries, showing that a multilayer MXene suspension with up to 70 wt % can exhibit flowability. Processing guidelines for the fabrication of MXene films, coatings, and fibers have been established based on the rheological properties. Surprisingly, high viscosity was ... |
| Databáze: | OpenAIRE |
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