The Identification of Toxic Compounds in the Pyrolysis Products of Polytetrafluoroethylene (PTFE)
Autor: | Richard E. Kupel, Robert L. Larkin, W. Emile Coleman, Lester D. Scheel |
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Rok vydání: | 1968 |
Předmět: |
Chromatography
Gas Hot Temperature Polytetrafluoroethylene Infrared Rays Chemistry Spectrum Analysis Public Health Environmental and Occupational Health Environmental Exposure Atmospheric temperature range Rats chemistry.chemical_compound Fluorocarbon Polymers Animals Organic chemistry Pyrolysis Nuclear chemistry |
Zdroj: | American Industrial Hygiene Association Journal. 29:33-40 |
ISSN: | 0002-8894 |
DOI: | 10.1080/00028896809342978 |
Popis: | When polytetrafluoroethylene (PTFE) was pyrolyzed in air in the temperature range of 500° to 650°C (932° to 1202°F), the predominate product was COF2. Above 650° C the major products were CF4 and CO2. Other fluorocarbons were produced in lesser amounts. PTFE pyrolyzed in the presence of SiO2 also formed SiF4. Between 550° and 600°C production of COF2 was as high as 63%. Experimental exposure of rats showed COF2 to be the most toxic component of the pyrolysis gases. |
Databáze: | OpenAIRE |
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