Photocatalytic Oxidative Cleavage of Alkenes by Molecular Oxygen: Reaction Scope, Mechanistic Insights, and Flow Application

Autor:	Yi-Lun Shih, Yen-Ku Wu, Mamoru Hyodo, Ilhyong Ryu
Rok vydání:	2022
Předmět:	Organic Chemistry
Zdroj:	The Journal of Organic Chemistry. 88:6548-6552
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.2c02429
Popis:	The oxidative cleavage of C═C bonds with molecular oxygen was promoted effectively by a catalytic amount of a decatungstate photocatalyst using black light irradiation (365 nm). Not only aromatic ketones but also aliphatic ketones were obtained by the photocatalytic protocol. The continuous flow reaction of α-methylstyrene using a high-power ultraviolet light-emitting diode (365 nm) dramatically decreased the reaction time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::79660ef9b55f3fc6a3c4ca830122ead0 https://doi.org/10.1021/acs.joc.2c02429 Zobrazit plný text záznamu