Kinetic applications of electron paramagnetic resonance spectroscopy. 35. The search for a dialkylaminyl rearrangement. Ring opening of N-cyclobutyl-N-n-propylaminyl

Autor:	Y. Maeda, K. U. Ingold
Rok vydání:	1980
Předmět:	Electron paramagnetic resonance spectroscopy Electron nuclear double resonance Chemistry General Chemistry Kinetic energy Ring (chemistry) Photochemistry Biochemistry Catalysis law.invention Colloid and Surface Chemistry law Physical chemistry Electron paramagnetic resonance
Zdroj:	Journal of the American Chemical Society. 102:328-331
ISSN:	1520-5126 0002-7863
Popis:	A search for a dialkylaminyl radical which rearranges at a rate suitable for study by kinetic EPR spectroscopy has shown that cyclobutyl-n-propylaminyl is such a species. This radical undergoes ring opening, and the rate constant for this process can be represented by log (kr/s-1) = (12.8 ± 1.5) - (10.5 ± 1.5)/θ, where θ = 2.3RT kcal/mol. © 1980 American Chemical Society.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::791091a1eb1d984e50d93cd7f3ae51de https://doi.org/10.1021/ja00521a052 Zobrazit plný text záznamu