A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium

Autor:	Paul G. Hayes, T. Don Tilley, Christopher W. Gribble, Rory Waterman
Rok vydání:	2009
Předmět:	Hydrogen Stereochemistry Ligand chemistry.chemical_element General Chemistry Biochemistry Catalysis Colloid and Surface Chemistry chemistry Polymer chemistry Osmium Extrusion Tin Isomerization
Zdroj:	Journal of the American Chemical Society. 131:4606-4607
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja901050m
Popis:	An osmium complex bearing a terminal hydrogen-substituted stannylene ligand, Cp*((i)Pr(3)P)(H)Os=SnH(trip) (1) (trip = 2,4,6-triisopropylphenyl), has been prepared by stannylene extrusion, and the complex has been structurally characterized. Complex 1 coordinates Lewis bases and activates the O-H bonds of water and methanol. Most interestingly, 1 converts to the metallostannylene complex Cp*((i)Pr(3)P)(H)(2)OsSn(trip) (2) thermally or photochemically by what appears to be a radical process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7909ad3d9c841797a6590b16cb971896 https://doi.org/10.1021/ja901050m Zobrazit plný text záznamu