Viscoelastic and Adhesion Properties of New Poly(Ether-Urethane) Pressure-Sensitive Adhesives
| Autor: | José Miguel Martín-Martínez, Mónica Fuensanta |
|---|---|
| Přispěvatelé: | Universidad de Alicante. Departamento de Química Inorgánica, Adhesión y Adhesivos |
| Rok vydání: | 2020 |
| Předmět: |
Polyurethane
Thermoplastic Materials science lcsh:Mechanical engineering and machinery Ether shear under creep 02 engineering and technology Industrial and Manufacturing Engineering chemistry.chemical_compound Crystallinity pressure-sensitive adhesive 0203 mechanical engineering Polyol Pressure-sensitive adhesive Viscoelastic properties General Materials Science lcsh:TJ1-1570 Prepolymer chemistry.chemical_classification probe tack Química Inorgánica peel Mechanical Engineering viscoelastic properties Adhesion 021001 nanoscience & nanotechnology Shear under creep Probe tack Computer Science Applications 020303 mechanical engineering & transports Peel chemistry Chemical engineering polyurethane Adhesive 0210 nano-technology |
| Zdroj: | RUA. Repositorio Institucional de la Universidad de Alicante Universidad de Alicante (UA) Frontiers in Mechanical Engineering, Vol 6 (2020) |
| Popis: | New thermoplastic poly(ether-urethane) (TPUs) pressure sensitive adhesives (PSAs) have been synthesized with the prepolymer method by reacting methylene diisocyanate, different blends of polyether diols poly(propyleneglycol) (PPG) and poly(tetramethylene ether glycol (PTMEG) , and 1,4-butanediol chain extender; different NCO/OH ratios have been used. The properties of the TPU PSAs depended on both the NCO/OH ratio and the PTMEG content in the blend. The addition of PTMEG polyol produced semicrystalline regions of the soft segments of the TPUs and inhibited the mobility of the polymeric chains, this leaded to improved cohesion of the TPU pressure sensitive adhesives; however, similar degrees of phase separation were obtained in all TPUs synthesized with different PTMEG contents. The increase of the PTMEG content in the polyols blend improved both the cohesion and the adhesion but decreased the tack of the TPU pressure sensitive adhesives. The optimal balance between the adhesion and cohesion properties was found in the TPU pressure sensitive adhesive synthesized with 50 wt% PPG + 50 wt% PTMEG and an NCO/OH ratio of 1.20. |
| Databáze: | OpenAIRE |
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