Concave Polyarenes with Sulfide-Linked Flaps and Tentacles: New Electron-Rich Hosts for Fullerenes

Autor: Anh Huu Tran, Paris E. Georghiou, Lawrence T. Scott, Mihail Bancu, Shehadeh Mizyed
Rok vydání: 2005
Předmět:
Zdroj: The Journal of Organic Chemistry. 70:6158-6163
ISSN: 1520-6904
0022-3263
DOI: 10.1021/jo0503761
Popis: Pentakis(1,4-benzodithiino)corannulene (6) in CS2 formed the strongest 1:1 complexes with C60 and C70 of any corannulene derivative yet reported. The 1,3,5,7,9-pentakis(propylthio)corannulene (4b) formed weaker 1:1 complexes with C60 and C70 in CS2, whereas the decakis(propylthio)corannulene (5b) and unsubstituted corannulene (1) showed no evidence for complexation with either C60 or C70 in CS2.
Databáze: OpenAIRE