Insertion of Oxygen and Nitrogen in the Siliceous Zeolite TON at High Pressure
| Autor: | Marta Morana, Kamil Dziubek, Mario Santoro, Roberto Bini, Gaston Garbarino, Demetrio Scelta, Federico A. Gorelli, Julien Haines, Francesco Di Renzo, Arie van der Lee, Jérôme Rouquette, Benoit Coasne |
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| Přispěvatelé: | European Laboratory for Non-Linear Spectroscopy (LENS), Università degli Studi di Firenze = University of Florence [Firenze] (UNIFI), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), European Synchroton Radiation Facility [Grenoble] (ESRF), Institut Européen des membranes (IEM), Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM), Laboratoire Interdisciplinaire de Physique [Saint Martin d’Hères] (LIPhy ), Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA) |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Materials science
chemistry.chemical_element [CHIM.MATE]Chemical Sciences/Material chemistry 010402 general chemistry 01 natural sciences Nitrogen Oxygen Diamond anvil cell 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials General Energy Chemical engineering chemistry High pressure 0103 physical sciences Ton [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat] Physical and Theoretical Chemistry Diatomic molecules Filling behavior Orientational orderings Oxygen and nitrogens Per unit Pore system Siliceous zeolite 010306 general physics Porous medium Zeolite ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Journal of physical chemistry. C. (Online) 125 (2021): 19517–19524. doi:10.1021/acs.jpcc.1c05083 info:cnr-pdr/source/autori:Santoro M.; Morana M.; Scelta D.; Rouquette J.; Dziubek K.; Gorelli F.A.; Bini R.; Garbarino G.; Van Der Lee A.; Di Renzo F.; Coasne B.; Haines J./titolo:Insertion of Oxygen and Nitrogen in the Siliceous Zeolite TON at High Pressure/doi:10.1021%2Facs.jpcc.1c05083/rivista:Journal of physical chemistry. C. (Online)/anno:2021/pagina_da:19517/pagina_a:19524/intervallo_pagine:19517–19524/volume:125 Journal of Physical Chemistry C Journal of Physical Chemistry C, American Chemical Society, 2021, 125 (35), pp.19517-19524. ⟨10.1021/acs.jpcc.1c05083⟩ |
| ISSN: | 1932-7447 1932-7455 |
| DOI: | 10.1021/acs.jpcc.1c05083 |
| Popis: | The insertion of oxygen and nitrogen molecules in the one-dimensional (1D) pore system of the zeolite TON was studied at high pressure by vibrational spectroscopy, X-ray diffraction, and Monte Carlo (MC) molecular modeling. Rietveld refinements and MC modeling indicate that, on average, six diatomic molecules per unit cell enter the pores of the zeolite. This induces changes in compressibility and distortion related to the Cmc21-to-Pbn21 phase transition compared to the empty-pore material. The filling behavior with N2 and O2 under pressure is similar to that of argon, suggesting that the kinetic diameter, which is very close in these three systems, plays a major role. The orientation of the diatomic molecules appears to have a rather minor effect on filling occurring at a slightly higher pressure for N2, which has a larger kinetic diameter. Both inserted molecules, initially not showing any marked orientation, begin to exhibit a degree of orientational order above 2 GPa. |
| Databáze: | OpenAIRE |
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