Femtosecond laser-matter interactions in ternary zinc phosphate glasses
Autor: | Hernandez-Rueda, J., Troy, N. W., Freudenberger, P., Brow, R. K., Krol, D. M., Sub Nanophotonics, Physics research: Debye Institute for Nanomaterials Science, Sub Physics of Condensed Matters begr, Nanophotonics |
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Přispěvatelé: | Sub Nanophotonics, Physics research: Debye Institute for Nanomaterials Science, Sub Physics of Condensed Matters begr, Nanophotonics |
Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Materials science
Analytical chemistry chemistry.chemical_element 02 engineering and technology Zinc Optical Physics 01 natural sciences Waveguide (optics) law.invention 010309 optics symbols.namesake chemistry.chemical_compound law 0103 physical sciences Electronic Nanotechnology Optical and Magnetic Materials Magnesium phosphate Zinc phosphate 021001 nanoscience & nanotechnology Laser Electronic Optical and Magnetic Materials chemistry Femtosecond symbols 0210 nano-technology Raman spectroscopy Ternary operation |
Zdroj: | Optical Materials Express, vol 8, iss 12 Optical Materials Express, 8(12), 3622. The Optical Society |
ISSN: | 2159-3930 |
DOI: | 10.1364/ome.8.003622 |
Popis: | We investigate the interaction of ultrashort laser pulses with ternary zinc phosphate glasses. We explore the viability of ten different glass compositions with different levels of alumina to inscribe optical waveguides via the fs-laser direct writing technique, finding that only samples with [O]/[P] ratios of 3.25 are suitable candidates. We also test a zinc magnesium phosphate glass to fabricate waveguide Bragg gratings in order to generate filters and mirrors with specific spectral properties. Confocal Raman spectroscopy inspection shows that laser-damaged material exhibits a relative intensity decrease and a subtle blue-shift on the 1209 cm-1 Raman peak, which implies a relative reduction on the content of Q(2) tetrahedra species within the glass network thus suggesting a laser-induced depolymerization. In contrast, optical waveguides and smooth laser-induced changes do not exhibit such noticeable structural modifications. |
Databáze: | OpenAIRE |
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