Coherent excitation of wavepackets in two electronic states. Interference effects at an avoided crossing

Autor:	Maurizio Persico, Giovanni Granucci
Rok vydání:	1995
Předmět:	Physics Excited state Avoided crossing General Physics and Astronomy Model system Physical and Theoretical Chemistry Atomic physics Potential energy Quantum Excitation Dissociation (chemistry) Electronic states
Zdroj:	Chemical Physics Letters. 246:228-234
ISSN:	0009-2614
Popis:	We present quantum mechanical calculations of the nonadiabatic time-evolution of molecular states in a model system. The simultaneous coherent excitation of two different electronic states is simulated. The repulsive potential energy curves representing the excited states undergo an avoided crossing, which causes the interference of the two wavepackets. The effect of interference on the final populations after dissociation exhibits a characteristic pattern as a function of the exciting radiation frequency.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7851a83bc873c342a56215a1fa8a49fd https://doi.org/10.1016/0009-2614(95)01118-s Zobrazit plný text záznamu Full Text from ScienceDirect