Two novel mixed-ligand zinc-acesulfame compounds: Synthesis, spectroscopic and thermal characterization and biological applications
| Autor: | Ömer Yurdakul, Gülçin Alp Avcı, Dursun Ali Köse, Onur Şahin |
|---|---|
| Přispěvatelé: | [Belirlenecek], Hitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
3-Aminopyridine
Acesulfame chemistry.chemical_element Zinc Triclinic crystal system 010402 general chemistry 01 natural sciences Enterococcus faecalis Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Agar diffusion test Thermal analysis Spectroscopy Benzotriazole biology Biological applications 010405 organic chemistry Organic Chemistry biology.organism_classification 0104 chemical sciences chemistry Monoclinic crystal system Nuclear chemistry |
| Popis: | Two new tetrahedral acesulfame complexes, acesulfamato(N)acesulfamato(O)bis(3-aminopyridine) zinc(II) (C18H20N6O8S2Zn, Zn-ace-3ap) and bis(acesulfamato-O)bis(benzotriazole)zinc(II) (C20H18N8O8S2Zn, Zn-ace-bta), were synthesized and characterized by single crystal X-ray diffraction, FT-IR spectroscopy, elemental analysis and thermal analysis techniques(TGA, DTA, DTG). The first compound, Zn-ace-3ap, crystallizes in triclinic space group P1 with parameters a = 7.978 (7) Å, b = 9.907 (6) Å, c = 15.778 (14) Å, ? = 78.24° (2), ? = 81.22° (4), ? = 75.99° (2), Z = 2 and The second compound, Zn-ace-bta, crystallizes in monoclinic space group C2/c with parameters a = 19.879 (3) Å, b = 9.3637 (13) Å, c = 14.0852 (18) Å, ? = 105.483° (4), Z = 4. The biological activities of the synthesized complexes were appraised through disk diffusion method as antibacterial, antimicrobial and antifungal in DMSO. Enterococcus faecalis (ATCC-29212), Staphylococcus aureus (ATCC-25923) as gram-positive bacteria, Pseudomonas aeroginosa (ATCC-27853) and Escherichia coli (ATCC-25922) as gram-negative bacteria, and Candida albicans (ATCC-10231) as fungus were grown with a view to investigate the antimicrobial effects of the complexes. 2-s2.0-85075379497 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|