Raman Spectroscopic Differences between Ephedrine and Pseudoephedrine
| Autor: | Tianmin Shu, Wenbo Li, Xiaojun Yao, Xing Yang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Resonance Raman spectroscopy Analytical chemistry Spectrum Analysis Raman 01 natural sciences Spectral line Pathology and Forensic Medicine 03 medical and health sciences symbols.namesake 0302 clinical medicine Genetics medicine Humans 030216 legal & forensic medicine Ephedrine Spectroscopy Density Functional Theory Molecular Structure 010401 analytical chemistry Pseudoephedrine 0104 chemical sciences Excited state symbols Central Nervous System Stimulants Density functional theory Raman spectroscopy medicine.drug |
| Zdroj: | Journal of Forensic Sciences. 64:1482-1485 |
| ISSN: | 1556-4029 0022-1198 |
| DOI: | 10.1111/1556-4029.14015 |
| Popis: | Ephedrine (EPH) and pseudoephedrine (PSE) were studied by micro-Raman spectroscopy and UV resonance Raman spectroscopy excited at 785 and 360 nm, respectively. Raman bands at approximately 245 and 410 cm-1 for ephedrine have apparent differences from the same bands at approximately 215, 265, 350, 450, and 555 cm-1 for pseudoephedrine, and these differences can be applied to distinguish between EPH and PSE. Additionally, density functional theory was used for the Raman calculations to obtain results identical to the experimental spectra. This work is expected to expand the applications of Raman spectroscopy in forensic science. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text