catena-Poly[[[bis(thiourea-κS)cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N] dihydrate]

Autor: Jarosław Chojnacki, Anna Mietlarek-Kropidłowska
Rok vydání: 2012
Předmět:
Zdroj: Acta Crystallographica Section E: Structure Reports
ISSN: 1600-5368
DOI: 10.1107/s1600536812030267
Popis: The title compound, {[Cd(NCS)2(CH4N2S)2]·2H2O}n, forms a one-dimensional chain parallel to theaaxis, caused by the presence of the bridging thiocyanate groups. Two solvent molecules per complex are present in the lattice. The CdIIion is situated on an inversion centre and is coordinated in a distorted octahedral fashion by two N and two S atoms from four thiocyanate ligands and by two S atoms from two thiourea molecules. Weak O—H...S, N—H...O and N—H...N interactions reinforce the structure.
Databáze: OpenAIRE