Highly selective electrosynthesis of biphenols on graphite electrodes in fluorinated media

Autor: Gregor Schnakenburg, Itamar Michael Malkowsky, Florian Stecker, Siegfried R. Waldvogel, Toshio Fuchigami, Axel Kirste, Shotaro Hayashi, Andreas Fischer
Rok vydání: 2011
Předmět:
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany). 17(50)
ISSN: 1521-3765
Popis: The direct and selective phenol coupling reaction that provides biphenols still represents a challenge in organic synthesis. The recently developed electrosynthesis on boron-doped diamond anodes with fluorinated additives was developed further to allow the application to less-expensive electrodes and fluorinated media. This advanced protocol allows the highly selective anodic phenol coupling reaction on graphite with a broad scope.
Databáze: OpenAIRE