Functionalization and exfoliation of graphite with low temperature pulse plasma in distilled water

Autor: Adrien Letoffé, Stéphane Cuynet, Cédric Noel, Ludovic de Poucques, Isabelle Royaud, Claire Hérold, Gérard Henrion, Marc Ponçot, Sébastien Fontana
Rok vydání: 2022
Předmět:
Zdroj: Physical Chemistry Chemical Physics. 24:5578-5589
ISSN: 1463-9084
1463-9076
Popis: Graphene materials exhibit extraordinary properties, but are difficult to produce. The present work describes the possibility of using a plasma process to exfoliate and functionalize graphite flakes. An impulse plasma phase is generated at a liquid surface to produce chemical species and shock waves in order to modify the reactive liquid as well as the graphite flakes. With this process, industrial graphite was treated. 20% thickness diminution was observed, and the formation of a random turbostratic structure. The exfoliation occurs with small amount of functionalization of the surface. Even after treatment, the graphite flakes present a low defect density compared with other treated graphite obtained by more conventional chemical treatments. This process is a new way to exfoliate graphite and to produce functionalized graphenic materials.
Databáze: OpenAIRE