Oxidative Dearomatization of o-Hydroxymethylphenol and Intramolecular π4s+π2s Cycloaddition: An Expedient Synthesis of a Tricyclic Intermediate for Platencin
| Autor: | Shaikh M. Mobin, Vishwakarma Singh, Beauty Das |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Platensimycin Enantioselective Synthesis Organic-Synthesis Inhibitor General-Route Formal Total-Synthesis fungi Organic Chemistry Oxidative Dearomatization Oxidative phosphorylation Key features Combinatorial chemistry Ring-Closing Metathesis Cycloaddition Spiroepoxycyclohexa-2 4-Dienone Intramolecular Diels-Alder Reaction chemistry Intramolecular force Antibiotic Properties (-)-Platensimycin Organic chemistry Diels-Alder Reaction Tricyclic |
| Zdroj: | Synlett. 24:1583-1587 |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/s-0033-1339196 |
| Popis: | A synthesis of a tricyclic intermediate for platencin from a simple aromatic precursor is described. Oxidative dearomatization and intramolecular Diels-Alder reaction are key features of the approach. |
| Databáze: | OpenAIRE |
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