Reaction of a Metallamacrocycle Leading to a Mercury(II)⋅⋅⋅Palladium(II)⋅⋅⋅Mercury(II) Interaction

Autor:	Ray J. Butcher, Sagar Sharma, Rajesh S. Baligar, Harkesh B. Singh
Rok vydání:	2009
Předmět:	chemistry Inorganic chemistry Polymer chemistry chemistry.chemical_element General Chemistry Catalysis Mercury (element) Palladium
Zdroj:	Angewandte Chemie International Edition. 48:1987-1990
ISSN:	1521-3773 1433-7851
DOI:	10.1002/anie.200805121
Popis:	All wrapped up: The reaction of a 22-membered macrocycle derived from bis(o-formylphenyl)mercury and 1,2-phenylenediamine with palladium(II) results in cleavage of the macrocycle and concomitant formation of a trimetallic complex (see picture; phenyl rings truncated for clarity). The nature of the Hg(II)...Pd(II)...Hg(II) interaction was investigated by theoretical studies.
Databáze:	OpenAIRE
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