Estimation of activation parameters for the propagation rate constant of styrene
| Autor: | WJ Wieb Kingma, Bart G. Manders, Anton L. German, Alex M. van Herk, Bert Klumperman, Grégory Chambard |
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| Přispěvatelé: | Chemical Engineering and Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 1996 |
| Předmět: |
Arrhenius equation
Polymers and Plastics Chemistry Estimation theory Organic Chemistry Thermodynamics Activation energy Atmospheric temperature range Confidence interval Styrene chemistry.chemical_compound symbols.namesake Reaction rate constant Polymer chemistry Materials Chemistry symbols Constant (mathematics) |
| Zdroj: | Journal of Polymer Science, Part A: Polymer Chemistry, 34(12), 2473-2479. Wiley |
| ISSN: | 1099-0518 0887-624X |
| DOI: | 10.1002/(SICI)1099-0518(19960915)34:12<2473::AID-POLA21>3.0.CO;2-4 |
| Popis: | For a temperature range of −11.8–92.6°C, the propagation rate constant kp of styrene has been determined with the use of pulsed-laser polymerization (PLP). The temperature dependency of the obtained kp data was evaluated using the Arrhenius equation. The NLLS error-in-variables method (EVM) is recommended for this fit. The resulting activation energy is 32.6 kJ mol−1 and the pre-exponential factor is 107.66 dm3 mol−1 s−1. A joint confidence interval for these parameters is given. © 1996 John Wiley & Sons, Inc. |
| Databáze: | OpenAIRE |
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