Microstructure and mechanical properties of cast in-situ TiAl matrix composites reinforced with (Ti,Nb)2AlC particles

Autor: Zuzana Gabalcová, A. Klimová, Oto Bajana, Juraj Lapin, T. Pelachová, Michaela Štamborská
Rok vydání: 2017
Předmět:
Zdroj: Materials & Design, Vol 133, Iss, Pp 404-415 (2017)
ISSN: 0264-1275
DOI: 10.1016/j.matdes.2017.08.012
Popis: The in-situ TiAl matrix composites with nominal compositions of Ti-44.5Al-8Nb-0.8Mo-0.1B-xC (at.%), where x is ranging from 1.4 to 4.8 at.%, were prepared by casting. The microstructure of the as-cast composites consists of primary (Ti,Nb)2AlC particles distributed in the matrix composed of lamellar γ(TiAl) + α2(Ti3Al) and γ phase regions with a small amount of β/B2 phase. The chemical composition of some coarse carbides is not homogeneous and central regions enriched by C are identified to be (Ti,Nb)C phase. The mean aspect ratio of the primary carbide particles decreases and their volume fraction and shape factor increase with increasing content of C. A linear relationship is identified between the volume fraction of the carbide particles and average content of C in the composites. The heat treatments lead to the formation of fine secondary carbide particles within the matrix. The mean grain size of the as-cast composites increases during the heat treatments. The Vickers hardness, compression yield strength, Charpy impact value and dynamic fracture toughness of the heat-treated composites decrease with the increasing volume fraction of carbide particles. The brittle fracture behaviour of the in-situ composites includes crack deflection, delamination on the matrix-carbide interfaces and pull-out of the carbide particles from the γ matrix. Keywords: Titanium aluminides, TiAl, Composites, Microstructure, Mechanical properties
Databáze: OpenAIRE