Diphenylalanine in tetrahydrofuran: a highly potent candidate for the development of novel nanomaterials
| Autor: | Anna Mitraki, Evangelos Georgilis, Renate Gessmann, Kyriacos Petratos |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Dipeptide Peptide 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Combinatorial chemistry Acceptor 0104 chemical sciences Nanomaterials Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Methanol Physical and Theoretical Chemistry Diphenylalanine 0210 nano-technology Tetrahydrofuran |
| Zdroj: | Acta crystallographica. Section C, Structural chemistry. 73(Pt 6) |
| ISSN: | 2053-2296 |
| Popis: | The peptide di-L-phenylalanine (FF) has emerged as a highly potent candidate for the development of novel nanomaterials. The unprotected peptide was dissolved in 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) mixed with tetrahydrofuran (THF) and single crystals of the THF monosolvate, C18H20N2O3·C4H8O, were grown by slow evaporation in a `vial-in-closed-bottle' system. THF is a molecule that can only act as a hydrogen-bond acceptor. Thus, the hydrogen-bond patterns observed in the crystal structures at 100 and 299 K are different compared to that of crystals grown from water and methanol [Mason et al. (2014). ACS Nano. 8, 1243–1253]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|