Surface-mounted MOF templated fabrication of homochiral polymer thin film for enantioselective adsorption of drugs

Autor:	Wen-Qiang Fu, Jian Zhang, Zhi-Gang Gu, Min Liu
Rok vydání:	2017
Předmět:	Fabrication Materials science Polymers Surface Properties Ultraviolet Rays 02 engineering and technology 010402 general chemistry 01 natural sciences Catalysis chemistry.chemical_compound Naproxen Adsorption Etching (microfabrication) Materials Chemistry Organic chemistry Thin film Porosity Metal-Organic Frameworks technology industry and agriculture Metals and Alloys Enantioselective synthesis Stereoisomerism General Chemistry 021001 nanoscience & nanotechnology Dihydroxyphenylalanine 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Monomer chemistry Chemical engineering Ceramics and Composites Metal-organic framework 0210 nano-technology
Zdroj:	Chemical Communications. 53:1470-1473
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c6cc08342k
Popis:	A self-polymerized chiral monomer 3,4-dihydroxy-l-phenylalanine (l-DOPA) has been introduced into the pores of an achiral surface-mounted metal organic framework (SURMOF), and then the homochiral poly(l-DOPA) thin film has been successfully formed after UV light irradiation and etching of the SURMOF. Remarkably, such a poly(l-DOPA) thin film exhibited enantioselective adsorption of naproxen. This study opened a SURMOF-templated approach for preparing porous polymer thin films.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76e950d5145bd1ed0433510d993a1a4a https://doi.org/10.1039/c6cc08342k Zobrazit plný text záznamu