Analysis of the structural, electronic, elastic and thermodynamic properties of CuAl2X4 (X = O, S) spinel structure
| Autor: | Yasemin Oztekin Ciftci, Mohammed M. Obeid, Y. Mogulkoc, M.M. Hussein Al-Marzooqee, Shaker J. Edrees, Majid M. Shukur |
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| Rok vydání: | 2018 |
| Předmět: |
010302 applied physics
Phase transition Materials science Mechanical Engineering Spinel Thermodynamics 02 engineering and technology engineering.material 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences symbols.namesake Lattice constant Mechanics of Materials 0103 physical sciences CASTEP symbols engineering General Materials Science Direct and indirect band gaps 0210 nano-technology Electronic band structure Ground state Debye model |
| Zdroj: | Materials Research Bulletin. 108:255-265 |
| ISSN: | 0025-5408 |
| DOI: | 10.1016/j.materresbull.2018.09.013 |
| Popis: | The structural, electronic, elastic and thermodynamic properties of oxo- and thio-spinels have been predicted based on the ultrasoft pseudo-potential scheme as implemented in the CASTEP code. The exchange-correlation potential was treated within the generalized gradient approximation (GGA-PBE). The calculated structural parameters such as lattice constants and internal parameters are in good agreement with the available experimental data. The ground state electronic band structure revealed that CuAl 2X4 (X O, S) spinels are direct band gap semiconductors with a transition along Г-Г symmetry points. The calculated values of elastic constants satisfy the Born criteria at ambient conditions and confirm that the spinel structures of CuAl2O4 and CuAl2S4 are mechanically stable. The thiospinel structure may have a phase transition under pressure, due to the negative value of C44. The influence of temperature and pressure on macroscopic characteristics of CuAl2O4 and CuAl2S4 compounds was estimated using the quasi-harmonic Debye model. |
| Databáze: | OpenAIRE |
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