The Structure of Poly(1-oxo-2-phenyltrimethylene): A Crystalline Alternating Styrene-Carbon Monoxide Copolymer

Autor:	P. CORRADINI, A. PANUNZI, G. PETRUCCI, P. PINO, DE ROSA, CLAUDIO
Přispěvatelé:	P., Corradini, DE ROSA, Claudio, A., Panunzi, G., Petrucci, P., Pino
Jazyk:	němčina
Rok vydání:	1990
Předmět:	Chemistry General Medicine General Chemistry QD1-999
Zdroj:	CHIMIA, Vol 44, Iss 3 (1990)
ISSN:	2673-2424 0009-4293
Popis:	From the alternating copolymerization of carbon monoxide and styrene with a soluble palladium containing catalytic system a product fraction insoluble in boiling 2-butanone was isolated which is highly crystalline. The polymer has been identified mainly by 1H- and 13C-NMR spectroscopy and by X-ray diffraction as syndiotactic poly(1-oxo-2-phenyltrimethylene). This polymer completely epimerizes to atactic poly(1-oxo-2-phenyltrimethylene) in the presence of sodium 2-chlorophenolate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::762e883c5b974ea163896ca5658b027e https://www.chimia.ch/chimia/article/view/1885 Zobrazit plný text záznamu