Meso-Microporous Nanosheet-Constructed 3DOM Perovskites for Remarkable Photocatalytic Hydrogen Production

Autor: Heng Zhao, Jing Liu, Chao‐Fan Li, Xu Zhang, Yu Li, Zhi‐Yi Hu, Bei Li, Zhangxin Chen, Jinguang Hu, Bao‐Lian Su
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Advanced functional materials. 32(22)
ISSN: 1616-3028
1616-301X
DOI: 10.1002/adfm.202112831
Popis: Three-dimensionally ordered macroporous (3DOM) structures have been widely utilized to largely enhance a photocatalytic activity. However, the common nanoparticles-constructed 3DOM photocatalysts possess numerous grain boundaries, unavoidably leading to a fast recombination of photogenerated electrons and holes. Herein, for the first time, a hierarchically two-dimensional (2D) meso-microporous perovskite nanosheet-constructed 3DOM CaTiO3 to significantly reduce the grain boundaries is designed and fabricated. Using carbon quantum dots (CQDs) as a metal-free co-catalyst, the 3DOM CQDs-CaTiO3 exhibits an outstanding photocatalytic activity for hydrogen generation of 0.13 mmol h−1 (20 mg photocatalyst) with remarkable apparent quantum efficiency (QAY) of 14.55% at 365 nm monochromatic light. This unprecedented performance is endowed by the synergy of a macro-meso-microporosity architecture, a large surface area, enhanced light harvesting, and improved charge carriers separation and transport. Density functional theory calculations and finite difference time-domain simulations further reveal the mechanism behind the enhanced separation of photogenerated electrons and holes. The present work demonstrates a trial on rationally designing meso-microporous nanosheet-constructed 3DOM perovskites for solar driven hydrogen production.
Databáze: OpenAIRE
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