Fe content effects on structural, electrical and magnetic properties of Fe-doped ITO polycrystalline powders
| Autor: | S.W. da Silva, D.G. Pacheco-Salazar, Renato Cohen, Luiz Carlos Camargo Miranda Nagamine, F. H. Aragón, J.A.H. Coaquira |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Ionic radius
Materials science Mechanical Engineering Metals and Alloys Analytical chemistry 02 engineering and technology ESPECTROSCOPIA RAMAN 010402 general chemistry 021001 nanoscience & nanotechnology Bixbyite 01 natural sciences 0104 chemical sciences Indium tin oxide Paramagnetism symbols.namesake Magnetization Transition metal Mechanics of Materials Materials Chemistry symbols 0210 nano-technology Raman spectroscopy Sheet resistance |
| Zdroj: | Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual) Universidade de São Paulo (USP) instacron:USP |
| Popis: | Fe-doped indium tin oxide (ITO) is an exciting material because it combines the host matrix's good electrical conductivity with the magnetic properties coming from the most earth-abundant transition metal, Fe. In this regard, a single-pot synthesis route based on a polymeric precursor method has been used to produce high-quality undoped and iron-doped ITO with iron content up to 13.0 mol%. The crystal formation in the bixbyite-type structure of all samples is confirmed by X-ray diffraction data analysis. A monotonous decrease of the lattice parameters with the increase of the Fe content is determined, which is consistent with of Fe ions with an oxidation state of 3+ in agreement with the ionic radii difference between In3+ and Fe3+. Raman spectroscopy confirms the bixbyite structure formation and provides evidence of a high surface disorder. 119Sn Mossbauer spectroscopy reveals the formation of only Sn4+ ions. Meanwhile, 57Co Mossbauer spectroscopy suggests the presence of Fe3+ ions in a paramagnetic state. DC magnetization characterization of the Fe-doped ITO nanoparticles confirms the compound's paramagnetic character. The sheet resistance (R/□) measurements provide a lower value for the undoped ITO sample (~0.26 Ω/sq) than the one of commercial bulk material. It has been determined that the sheet resistance increases with the Fe content, suggesting the decrease of the conduction electrons density as the iron content is increased. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|