Effect of cellulose structure and morphology on the properties of poly(butylene succinate-co-butylene adipate) biocomposites
| Autor: | Maurizio Avella, Maria Emanuela Errico, Roberto Avolio, Veronica Ambrogi, Mariacristina Cocca, V. Graziano, Y. D. F. Pereira, Gennaro Gentile |
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| Přispěvatelé: | Avolio, R, Graziano, V., Pereira, Y. D. F., Cocca, M., Gentile, G., Errico, M. E., Ambrogi, Veronica, Avella, M. |
| Rok vydání: | 2015 |
| Předmět: |
Thermogravimetric analysis
Succinate Materials science Epoxy Compound Polymers and Plastics Adipates Methacrylate Permeability chemistry.chemical_compound Crystallinity Tensile Strength Adipate Materials Chemistry Cellulose Composite material Maleic Anhydride Filler Maleic Anhydrides Materials Chemistry2506 Metals and Alloy chemistry.chemical_classification Biocomposites Polymers and Plastic Medicine (all) Organic Chemistry Structure Water Chemical modification Maleic anhydride Succinates Polymer Polybutylene succinate chemistry Epoxy Compounds Methacrylates Volatilization Biocomposite PBSA |
| Zdroj: | Carbohydrate polymers 133 (2015): 408–420. doi:10.1016/j.carbpol.2015.06.101 info:cnr-pdr/source/autori:Avolio, R.; Graziano, V.; Pereira, Y. D F; Cocca, M.; Gentile, G.; Errico, M. E.; Ambrogi, V.; Avella, M./titolo:Effect of cellulose structure and morphology on the properties of poly(butylene succinate-co-butylene adipate) biocomposites/doi:10.1016%2Fj.carbpol.2015.06.101/rivista:Carbohydrate polymers/anno:2015/pagina_da:408/pagina_a:420/intervallo_pagine:408–420/volume:133 |
| ISSN: | 0144-8617 |
| DOI: | 10.1016/j.carbpol.2015.06.101 |
| Popis: | Composites based on poly(butylene succinate-co-butylene adipate) (PBSA) containing amorphized and crystalline cellulose reinforcements have been prepared and characterized. In order to improve the polymer/filler interfacial adhesion, an efficient compatibilizing agent has been synthesized by chemical modification of PBSA and characterized by FT-IR, FT-NIR and 1H NMR spectroscopy. Uncompatibilized and compatibilized composites have been tested through morphological, mechanical, calorimetric and thermogravimetric analysis. Moreover, water vapor permeability and biodegradation kinetics of composites have been investigated. The addition to PBSA of cellulose fillers differing from each other by crystallinity degree and morphology, and the use of a compatibilizing agent have allowed modulating tensile and thermal properties, water vapor transmission rate and biodegradation kinetic of the composites. |
| Databáze: | OpenAIRE |
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