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Gold nuggets have long captured the imagination of geologists, prospectors and the public alike, but their origin remains disputed. Supporting a supergene origin, most gold nuggets in Australia have been found at or near the soil surface. Many are intimately associated with, and even appear to enclose, soil materials and weathered rock. Even large nuggets (e.g., >2 kg) have surface features and/or gross morphologies that suggest chemical reworking in the regolith. Conversely, other nuggets have been found at depths of ten metres or more in the regolith, and large masses of gold have been encountered at considerable depth, in completely unweathered, hypogene environments. Nuggets and particulate gold from many deposits in Australia, New Guinea, SE Asia and Brazil have been examined by optical and electron-optical techniques to determine characteristics that may indicate their genesis and stability in the regolith. The specimens have been collected at or close to the surface but all nuggets (mass range ~1 gm to >8 kg) and many smaller grains appear to be hypogene. They have nearly homogeneous Ag contents, mostly in the range 3 to 20 wt%, although some have no detectable Ag. One specimen also contains up to 3 wt% Hg, but no other alloyed metals > 0.1 wt% were detected. Enclosed minerals are rare – with only galena, Bi sulphide, galenobismutite and complex Ag-Hg tellurides in a few samples. The internal structure of the nuggets comprises nearly equigranular, randomly-oriented crystal domains. Many crystals display coherent twins and/or short incoherent twins that terminate within the crystal, all typical of thermal annealing at temperatures >250°C. Some small nuggets from SE Asia, also with annealing fabrics are possibly the product of hydrothermal remobilization and re-precipitation. In comparisons, some specimens from New Guinea contain 10->30 wt% Ag and have internal structures such as zoning and ‘fern-like’ crystal habits. These are derived from epithermal deposits and have not been deformed or recrystallized since initial deposition. Even the largest nuggets have internal evidence of weathering. Many have secondary minerals such as Fe oxides, clays and calcite within them, but none of these is fully enclosed. Rather, they are all open to the outer margin of the nuggets, situated in interconnecting voids along crystal boundaries. These boundaries also exhibit Ag depletion, similar to the depletion rims on the external surface. EBSD analysis shows there is no variation in crystallographic orientation across, or into, the depletion zones. These characteristics show that nuggets are dissolving in the surface environment, not forming, with weathering reactions initiated on the external surface and, internally, along crystal boundaries. |
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