Iron(IV) complexes with tetraazaadamantane-based ligands: synthesis, structure, applications in dioxygen activation and labeling of biomolecules

Autor:	Ivan S. Golovanov, Anton V. Leonov, Vladislav K. Lesnikov, Evgeny V. Pospelov, Kirill V. Frolov, Alexander A. Korlyukov, Yulia V. Nelyubina, Valentin V. Novikov, Alexey Yu. Sukhorukov
Rok vydání:	2022
Předmět:	Inorganic Chemistry Models Molecular Oxygen Adamantane Crystallography X-Ray Ligands Density Functional Theory Iron Compounds
Zdroj:	Dalton transactions (Cambridge, England : 2003). 51(11)
ISSN:	1477-9234
Popis:	4,6,10-Trihydroxy-1,4,6,10-tetraazaadamantane (TAAD) has been shown to form a stable Fe(IV) complex having a diamantane cage structure, in which the metal center is coordinated by three oxygen atoms of the deprotonated ligand. The complex was characterized by X-ray diffraction analysis, HRMS, NMR, FT-IR, Mössbauer spectroscopy and DFT calculations, which supported the d
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::75155e437f0336ea18d4b1461d80c1c2 https://pubmed.ncbi.nlm.nih.gov/35191438 Zobrazit plný text záznamu