New triorganotin(IV) complexes of a polyfunctional S,N,O-ligand

Autor:	Mercedes Camalli, Riccardo Spagna, Simone Alidori, Carlo Santini, Marilena Mancini, Maura Pellei
Rok vydání:	2005
Předmět:	Chloroform Ethanol Stereochemistry Ligand Sodium 2-Mercaptopyridine chemistry.chemical_element Crystal structure Medicinal chemistry law.invention Inorganic Chemistry chemistry.chemical_compound chemistry law Materials Chemistry Physical and Theoretical Chemistry Diethyl ether Crystallization
Zdroj:	Polyhedron. 24:995-1001
ISSN:	0277-5387
Popis:	The new sodium bis(2-pyridylthio)acetate ligand, Na[(pyS)2CHCO2], has been prepared in ethanol solution using 2-mercaptopyridine, dibromoacetic acid and NaOH. New tri-organotin(IV) derivatives containing the anionic bis(2-pyridylthio)acetate have been synthesized from reaction between SnR3Cl (R = Me, nBu, Ph and Cy) acceptors and Na[(pyS)2CHCO2]. Complexes of the type {[(pyS)2CHCO2]SnR3}have been obtained and characterized by elemental analyses, FT-IR, ESI-MS, multinuclear (1H and 119Sn) NMR spectral data and X-ray crystallography. Crystallisation of the compound {[(pyS)2CHCO2]Sn(CH3)3}n, from chloroform/diethyl ether solution, yielded the complex {[(pyS)2CHCO2]Sn(CH3)3}n · CHCl3, which has been characterized by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::750f399b1d4abbebe3799d6eb872a5bf https://doi.org/10.1016/j.poly.2005.04.001 Zobrazit plný text záznamu Full Text from ScienceDirect