Reactivity Comparison of ω-Alkenols and Higher 1-Alkenes in Copolymerization with Propylene Using An Isospecific Zirconocene-MMAO Catalyst
| Autor: | Tianyou Li, Benard Oloo Nyangoye, Zhengguo Cai, Long Chen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
metallocene Materials science Polymers and Plastics Comonomer propylene Methylaluminoxane General Chemistry Polymer ω-alkenol copolymerization reactivity Catalysis lcsh:QD241-441 chemistry.chemical_compound Monomer chemistry lcsh:Organic chemistry Polymer chemistry Copolymer Reactivity (chemistry) Metallocene |
| Zdroj: | Polymers, Vol 7, Iss 10, Pp 2009-2016 (2015) Polymers; Volume 7; Issue 10; Pages: 2009-2016 Polymers Volume 7 Issue 10 Pages 2009-2016 |
| ISSN: | 2073-4360 |
| Popis: | Copolymerizations of propylene with ω-alkenols (aluminum-protected 5-hexene-1-ol (AH) and 10-undecene-1-ol (AU)) and non-polar analogues (1-hexene and 1-dodecene) were conducted with a rac-[Me2Si(2-Me-4-Ph-Ind)2]ZrCl2 activated by modified methylaluminoxane. The catalytic system showed high activity for each copolymerization, of which value was independent on the comonomer used and decreased with the increase of the comonomer concentration. The comonomer content of the copolymers obtained also decreased with the increase of the comonomer concentration in each copolymer. The evaluation of the monomer reactivity ratios indicates a preference for the propylene insertion regardless of the last inserted monomer unit in growing polymer chain in all the copolymerizations. The relative reactivity of ω-alkenols was however significantly lower than that of non-polar analogues. These results suggested that the aluminum protection of polar monomer do not affect the activity of copolymerization but significantly decrease the comonomer reactivity. |
| Databáze: | OpenAIRE |
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