Growth, morphology and electronic properties of epitaxial graphene on vicinal Ir(332) surface

Autor: François Nicolas, Daniel Malterre, Antonio Tejeda, A. Taleb-Ibrahimi, Stefan Kubsky, Arlensiú Celis, Muriel Sicot, Maya N. Nair
Přispěvatelé: Laboratoire de Physique des Solides (LPS), Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Synchrotron SOLEIL (SSOLEIL), Centre National de la Recherche Scientifique (CNRS), City University of New York [New York] (CUNY), Institut Jean Lamour (IJL), Université de Lorraine (UL)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nanotechnology
Nanotechnology, Institute of Physics, 2020, 31 (28), pp.285601. ⟨10.1088/1361-6528/ab866a⟩
ISSN: 0957-4484
1361-6528
DOI: 10.1088/1361-6528/ab866a⟩
Popis: International audience; Superlattice induced minigaps in graphene band structure due to underlying one-dimensional nanostructuration has been demonstrated. A superperiodic potential can be introduced in graphene if the substrate is periodically structured. The successful preparation of a periodically nanostructured substrate in large scale can be obtained by carefully studying the electronic structure with a spatial averaging technique such as high-energy resolution photoemission. In this work, we present two different growth methods such as temperature programmed growth (TPG) and chemical vapor deposition (CVD) studied by scanning tunnelling microscopy (STM) and low energy electron diffraction (LEED). In both methods, we show that the original steps of Ir(332) have modified with (111) terraces and step bunching after graphene growth. Graphene grows continuously over the terrace and the step bunching areas. We observe that while TPG growth does not give rise to a well-defined surface periodicity required for opening a bandgap, the CVD growth does. By combining with angle-resolved photoemission spectroscopy (ARPES) measurements, we correlate the obtained spatial periodicity to observed band gap opening in graphene.
Databáze: OpenAIRE