BINOL blocks as accessible triplet state modulators in BODIPY dyes

Autor:	Josué Jiménez, Ruth Prieto-Montero, Sergio Serrano, Patrycja Stachelek, Esther Rebollar, Beatriz L. Maroto, Florencio Moreno, Virginia Martinez-Martinez, Robert Pal, Inmaculada García-Moreno, Santiago de la Moya
Přispěvatelé:	Ministerio de Ciencia e Innovación (España), Royal Society (UK), European Commission, Biotechnology and Biological Sciences Research Council (UK), Eusko Jaurlaritza, Universidad Complutense de Madrid
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications, 2022, Vol.58(44), pp.6385-6388 [Peer Reviewed Journal] Digital.CSIC. Repositorio Institucional del CSIC instname
Popis:	4 pags., 4 figs., 1 tab. BINOL moieties of different electronic demand are useful blocks for enabling the photo-production and modulation of triplet excited states in readily-accesible BINOL-based O-BODIPY dyes from standard F-BODIPY precursors. The rapid and rational development of smarter triplet-enabling BODIPY dyes on the basis of this strategy (e.g., TADF biomarker 4a or room temperature phosphor 4g) paves the way for advancing photonic applications based on organic triplet photosensitizers. Financial support from MICINN (PID2020-114755GB-C32 and C-33, and PID2020-114347RB-C32), Royal Society (URF\R\191002), UE (H2020-MSCA-ITN-859752 and HEL4CHIROLED), BBSRC (BB/S017615/1) and Basque Government (IT1639-22) is gratefully acknowledged. J. J., R. P.-M. and P. S. respectively thank CM/UCM, MICINN (MARSA21/71) and BB/S017615/1 for research contracts.
Databáze:	OpenAIRE
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