Stability, reusability, and equivalent circuit of TiO2/treated metakaolinite-based dye-sensitized solar cell: effect of illumination intensity on Voc and Isc values
Autor: | Winda Rahmalia, Imelda H. Silalahi, Thamrin Usman, Zéphirin Mouloungui, Jean-François Fabre, Georges Zissis |
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Přispěvatelé: | Tanjungpura University, Partenaires INRAE, INP - ENSIACET, Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées, Chimie Agro-Industrielle (CAI), Ecole nationale supérieure des ingénieurs en arts chimiques et technologiques-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Lumière et Matière (LAPLACE-LM), LAboratoire PLasma et Conversion d'Energie (LAPLACE), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées, This study received financial support from the Ministry of Research Technology and Higher Education Republic of Indonesia (RISTEKDIKTI) |
Jazyk: | angličtina |
Rok vydání: | 2021 |
Předmět: |
Anatase
Equivalent circuit Materials science Band gap TJ807-830 chemistry.chemical_element 02 engineering and technology Electrolyte Energy conservation 010402 general chemistry 7. Clean energy 01 natural sciences Renewable energy sources [SPI.MAT]Engineering Sciences [physics]/Materials Materials Chemistry Energy transformation Renewable Energy Sustainability and the Environment Energy conversion efficiency Bixin 021001 nanoscience & nanotechnology Metakaolinite TJ163.26-163.5 0104 chemical sciences Electronic Optical and Magnetic Materials Light intensity Dye-sensitized solar cell Fuel Technology Photoelectrode chemistry Chemical engineering [SPI.OPTI]Engineering Sciences [physics]/Optics / Photonic 0210 nano-technology Carbon |
Zdroj: | Materials for Renewable and Sustainable Energy Materials for Renewable and Sustainable Energy, Springer, 2021, 10 (2), pp.10. ⟨10.1007/s40243-021-00195-9⟩ Materials for Renewable and Sustainable Energy, Vol 10, Iss 2, Pp 1-10 (2021) |
ISSN: | 2194-1459 |
DOI: | 10.1007/s40243-021-00195-9⟩ |
Popis: | In this research, treated metakaolinite (TMK) was introduced into the TiO2 photoelectrode to fabricated dye-sensitized solar cells (DSSCs). The photovoltaic cells have four main natural components, i.e., a photosensitizer (carotenoid bixin), photoelectrode (TiO2/kaolinite), electrolyte (glycerine carbonate derivative), and counter-electrode (carbon). Their stability, reusability, and equivalent circuit were studied. The presence of 5% of TMK in anatase TiO2 paste decreased the TiO2 band gap from 3.21 to 3.16 eV. The result showed that the presence of 5% of TMK in TiO2 paste was more favorable to obtain higher energy conversion efficiency. Under a light intensity of 200 W/m2, it produced an energy conversion yield of 0.086%. The combination of the electrolyte and the TMK demonstrated a synergistic effect to improve the electrical properties of the DSSC. The energy storage function worked well until the third day of analysis. The DSSC based on TiO2/TMK photoelectrode exhibited 16 times better stability than pure TiO2-based photoelectrode. The Faraday charge transfer processes showed that the TiO2/TMK photoelectrode is not in direct contact with the carbon counter-electrode. |
Databáze: | OpenAIRE |
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