Photoelectron recoil in CO in the x-ray region up to 7 keV
| Autor: | Maria Novella Piancastelli, Marc Simon, David Ayuso, Kuno Kooser, D. Iablonsky, Kiyoshi Ueda, S. Granroth, H. Levola, Oksana Travnikova, T. D. Thomas, Edwin Kukk, Ralph Püttner, Pietro Decleva, Denis Céolin, Tatiana Marchenko, Gildas Goldsztejn |
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| Přispěvatelé: | Kukk, E., Thomas, T. D., Ueda, K., Céolin, D., Granroth, S., Kooser, K., Travnikova, O., Iablonsky, D., Decleva, Pietro, Ayuso, D., Püttner, R., Levola, H., Goldsztejn, G., Marchenko, T., Piancastelli, M. N., Simon, M. |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Photon
Photoemission spectroscopy Physics::Instrumentation and Detectors 01 natural sciences Molecular physics Spectral line Recoil Atomic and Molecular Physics Optics 0103 physical sciences Franck-Condon factorsIntensity ratio Photoelectron spectrum Potential energy curves Recoil effect Vibrational intensities Vibrational progressions X-ray energies Physics::Atomic and Molecular Clusters Physics::Atomic Physics Physics::Chemical Physics 010306 general physics Morse potential Physics Range (particle radiation) 010304 chemical physics ta114 Rotational–vibrational spectroscopy Coupling (probability) Atomic and Molecular Physic Atomic physics |
| Zdroj: | Physical review. A (Online) 95 (2017). doi:10.1103/PhysRevA.95.042509 info:cnr-pdr/source/autori:Kukk E.; Thomas T.D.; Ueda K.; Ceolin D.; Granroth S.; Kooser K.; Travnikova O.; Iablonsky D.; Decleva P.; Ayuso D.; Puttner R.; Levola H.; Goldsztejn G.; Marchenko T.; Piancastelli M.N.; Simon M./titolo:Photoelectron recoil in CO in the x-ray region up to 7 keV/doi:10.1103%2FPhysRevA.95.042509/rivista:Physical review. A (Online)/anno:2017/pagina_da:/pagina_a:/intervallo_pagine:/volume:95 |
| DOI: | 10.1103/PhysRevA.95.042509 |
| Popis: | Carbon $1s$ photoelectron spectra of CO molecules in gas phase were recorded in the tender x-ray energy range, from 2.3 to 6.9 keV. The intensity ratios of individual peaks from $\ensuremath{\nu}=0$ to 3 within the vibrational progression of the C $1s$ photoelectron spectrum were determined at the various photon energies and are shown to be strongly affected by the photoelectron recoil effect. The experimental vibrational intensity ratios are compared with theoretical predictions at different levels of accuracy. Developments of the recoil model, using generalized Franck-Condon factors, rovibrational coupling, Morse potential energy curves, and accurate angular averaging are presented and applied to the analysis of the experimental results. |
| Databáze: | OpenAIRE |
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