A novel approach for rhodium(iii)-catalyzed C-H functionalization of 2,2'-bipyridine derivatives with alkynes: a significant substituent effect
| Autor: | Zhuo Wang, Bolin Zhu, Shaonan Wu, Yinwei Bao, Kun Liu, Chen Chen |
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| Rok vydání: | 2020 |
| Předmět: |
Chemistry
Metals and Alloys Substituent chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis 2 2'-Bipyridine Surfaces Coatings and Films Electronic Optical and Magnetic Materials Rhodium chemistry.chemical_compound Bipyridine Materials Chemistry Ceramics and Composites Surface modification |
| Zdroj: | Chemical communications (Cambridge, England). 56(32) |
| ISSN: | 1364-548X |
| Popis: | We described a novel approach for the C-H functionalization of 2,2'-bipyridine derivatives with alkynes. DFT calculations and experimental data showed a significant substituent effect at the 6-position of 2,2'-bipyridine, which weakened the adjacent N-Rh bond and provided the possibility of subsequent rollover cyclometalation, C-H activation, and functionalization. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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