Study of Aqueous HCI and Formaldehyde Mixtures for Formation of Bis (Chloromethyl) Ether
Autor: | James C. Tou, George J. Kallos |
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Rok vydání: | 1974 |
Předmět: |
Methyl Ethers
Occupational Medicine Chromatography Gas Formaldehyde Hydrochloric acid Ether Mass Spectrometry Gas phase chemistry.chemical_compound Air Pollution Organic chemistry Detection limit Aqueous solution Chemistry Public Health Environmental and Occupational Health Aqueous two-phase system Water Bis(chloromethyl) ether Solutions embryonic structures Carcinogens Methyl Chloride cardiovascular system Hydrochloric Acid Nuclear chemistry |
Zdroj: | American Industrial Hygiene Association Journal. 35:419-422 |
ISSN: | 0002-8894 |
DOI: | 10.1080/0002889748507053 |
Popis: | The reaction of aqueous HCI and formaldehyde at concentrations up to 2000 ppm were carried out at ambient temperature for 18 hours to investigate the possible formation of bis(chloromethyl)ether. Bis(chloromethyl)ether was not observed either in the aqueous phase or the gas phase above the reaction mixture, with detection limits of 9 ppb and 1 ppb, respectively. Strong inferential evidence shows that bis(chloromethyl)ether cannot be present at even a much lower level than 9 ppb in aqueous solution. |
Databáze: | OpenAIRE |
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