Supported Pd-Au membrane reactor for hydrogen production: Membrane preparation, characterization and testing
| Autor: | Jennifer Wilcox, Angelo Basile, Bryce H. Anzelmo, Simona Liguori, Marjan Alavi, Adolfo Iulianelli, Giuseppe Bagnato, Mohammad Reza Rahimpour, Reza Eslamlouyan |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Hydrogen
Surface Properties hydrogen production Pharmaceutical Science chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Article Analytical Chemistry Catalysis Steam reforming lcsh:QD241-441 lcsh:Organic chemistry Drug Discovery composite membrane SDG 7 - Affordable and Clean Energy Physical and Theoretical Chemistry membrane Hydrogen production methane steam reforming Pd-Au membrane Chromatography Membrane reactor Chemistry Organic Chemistry Permeation 021001 nanoscience & nanotechnology 0104 chemical sciences Steam Membrane Chemical engineering Chemistry (miscellaneous) hydrogen Molecular Medicine Gold 0210 nano-technology Methane Palladium Space velocity |
| Zdroj: | Iulianelli, A, Alavi, M, Bagnato, G, Liguori, S, Wilcox, J, Rahimpour, M R, Eslamlouyan, R, Anzelmo, B & Basile, A 2016, ' Supported Pd-Au membrane reactor for hydrogen production: Membrane preparation, characterization and testing ', Molecules . https://doi.org/10.3390/molecules21050581 Molecules, Vol 21, Iss 5, p 581 (2016) Molecules (Basel, Online) 21 (2016). doi:10.3390/molecules21050581 info:cnr-pdr/source/autori:Iulianelli A.; Alavi M.; Bagnato G.; Liguori S.; Wilcox J.; Rahimpour M.R.; Eslamlouyan R.; Anzelmo B.; Basile A./titolo:Supported Pd-Au membrane reactor for hydrogen production: Membrane preparation, characterization and testing/doi:10.3390%2Fmolecules21050581/rivista:Molecules (Basel, Online)/anno:2016/pagina_da:/pagina_a:/intervallo_pagine:/volume:21 Molecules; Volume 21; Issue 5; Pages: 581 Molecules |
| DOI: | 10.3390/molecules21050581 |
| Popis: | A supported Pd-Au (Au 7wt%) membrane was produced by electroless plating deposition. Permeation tests were performed with pure gas (H₂, H₂, N₂, CO₂, CH₄) for long time operation. After around 400 h under testing, the composite Pd-Au membrane achieved steady state condition, with an H₂/N₂ ideal selectivity of around 500 at 420 °C and 50 kPa as transmembrane pressure, remaining stable up to 1100 h under operation. Afterwards, the membrane was allocated in a membrane reactor module for methane steam reforming reaction tests. As a preliminary application, at 420 °C, 300 kPa of reaction pressure, space velocity of 4100 h(-1), 40% methane conversion and 35% hydrogen recovery were reached using a commercial Ni/Al₂O₃ catalyst. Unfortunately, a severe coke deposition affected irreversibly the composite membrane, determining the loss of the hydrogen permeation characteristics of the supported Pd-Au membrane. |
| Databáze: | OpenAIRE |
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