Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies

Autor: Jannik Junge, Sven Froitzheim, Tobias A. Engesser, Jan Krahmer, Christian Näther, Nicolas Le Poul, Felix Tuczek
Rok vydání: 2022
Předmět:
Zdroj: Dalton transactions (Cambridge, England : 2003). 51(16)
ISSN: 1477-9234
Popis: The tungsten dinitrogen complex [W(N2)(PMe2PPPh2)] is compared to its molybdenum analogue. Detailed (IR-spectro)electrochemical investigations were made. In the presence of SmI2/H2O the W complex mediates the conversion of N2 to 2.75 equiv. ammonia.
Databáze: OpenAIRE