Facile synthesis of 3-alkoxy-4-cyanothiophenes as new building blocks for donor-acceptor conjugated systems
| Autor: | Noémie Hergué, Charlotte Mallet, Gurunathan Savitha, Magali Allain, Jean Roncali, Pierre Frère |
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| Přispěvatelé: | MOLTECH-Anjou, Université d'Angers (UA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2011 |
| Předmět: |
Models
Molecular Cyanides Alkylation Molecular Structure 010405 organic chemistry Chemistry Organic Chemistry Thiophenes Conjugated system 010402 general chemistry Ring (chemistry) 01 natural sciences Biochemistry Combinatorial chemistry 3. Good health 0104 chemical sciences chemistry.chemical_compound Alkoxy group Structural isomer Thiophene [CHIM]Chemical Sciences Physical and Theoretical Chemistry Donor acceptor ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Organic Letters Organic Letters, American Chemical Society, 2011, 13 (7), pp.1762-1765. ⟨10.1021/ol200296j⟩ |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol200296j⟩ |
| Popis: | 3-Alkoxy-4-cyanothiophenes are efficiently synthesized in two steps from the readily available 4-cyano-3-oxotetrahydrothiophene. Regioisomers of bithiophene derivatives are easily synthesized by playing on the strong electronic dissymmetry of the thiophene ring induced by the alkoxy and cyano groups. |
| Databáze: | OpenAIRE |
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