Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(ii ) and Fe(iii ) compounds
Autor: | Song Gao, Bing-Wu Wang, Qiong Yuan, Tai-Chu Lau, Li-Xin Wang, Si-Huai Chen, Xiao-Fan Wu, Jing Xiang, Xin-Xin Jin, Qian-Qian Su |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Chemical Communications. 57:781-784 |
ISSN: | 1364-548X 1359-7345 |
Popis: | A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii) and Fe(iii) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour. The Fe(iii) compound represents the first example of 8-coordinate Fe(iii) single-molecule magnets (SMM). |
Databáze: | OpenAIRE |
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