Influence of silicate solution preparation on geomaterials based on brick clay materials
Autor: | Emmanuel Joussein, Sylvie Rossignol, Julie Peyne, J. Doudeau, J. Gautron |
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Přispěvatelé: | Axe 3 : organisation structurale multiéchelle des matériaux (SPCTS-AXE3), Science des Procédés Céramiques et de Traitements de Surface (SPCTS), Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Limoges (UNILIM)-Institut des Procédés Appliqués aux Matériaux (IPAM), Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Ecole Nationale Supérieure de Céramique Industrielle (ENSCI)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Limoges (UNILIM) |
Rok vydání: | 2017 |
Předmět: |
Materials science
0211 other engineering and technologies Mineralogy 02 engineering and technology Raw material [SPI.MAT]Engineering Sciences [physics]/Materials chemistry.chemical_compound symbols.namesake Aluminosilicate 021105 building & construction Materials Chemistry Fourier transform infrared spectroscopy ComputingMilieux_MISCELLANEOUS Alkaline earth metal Brick [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Alkali metal 6. Clean water Silicate Electronic Optical and Magnetic Materials chemistry Chemical engineering Ceramics and Composites symbols 0210 nano-technology Raman spectroscopy |
Zdroj: | Journal of Non-Crystalline Solids Journal of Non-Crystalline Solids, Elsevier, 2017, 471, pp.110-119. ⟨10.1016/j.jnoncrysol.2017.05.017⟩ |
ISSN: | 0022-3093 |
DOI: | 10.1016/j.jnoncrysol.2017.05.017 |
Popis: | Brick clay mixtures are raw materials with the potential for use in geomaterials other than tiles or bricks. This study concerns the effect of mixed alkali cation solutions on the polycondensation reactions of geomaterials based on brick clay mixtures. To evidence the feasibility and the understanding of such effects, FTIR and Raman spectroscopy, thermal analyses and compressive tests were investigated to reveal the performance of the alkaline solution and aluminosilicate source. The various solutions used contained different siliceous species (rings, chains) that modified the polycondensation reactions and the Si-O-Ca bond formation. The effect of the polarizability of the alkaline and alkaline earth solutions must be controlled to enhance the final properties. Better mechanical properties were obtained with a low water content. |
Databáze: | OpenAIRE |
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