NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation
| Autor: | Simon B. Duckett, Cyril Godard, Philip Callaghan, Jenny L. Cunningham, Joost A. B. Lohman, Robin N. Perutz |
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| Rok vydání: | 2002 |
| Předmět: |
In situ
chemistry.chemical_classification Alkene Inorganic chemistry Metals and Alloys chemistry.chemical_element General Chemistry Spin isomers of hydrogen Photochemistry Toluene Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Rhodium Solvent chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Irradiation |
| Zdroj: | Chemical communications (Cambridge, England). (23) |
| ISSN: | 1359-7345 |
| Popis: | Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene)rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable eta 2-solvent complexes and dihydrogen activation products. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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