Synthesis, Characterization, and Properties of High-Energy Fillers Derived from Nitroisobutylglycerol

Autor:	Sergey A. Rzhevskiy, Lidiya I. Minaeva, Maxim A. Topchiy, Igor N. Melnikov, Vitaly G. Kiselev, Alla N. Pivkina, Igor V. Fomenkov, Andrey F. Asachenko
Rok vydání:	2023
Předmět:	Inorganic Chemistry Organic Chemistry energetic compounds high-energy additives nitroisobutylglycerol comprehensive study physiochemical and energetic properties General Medicine Physical and Theoretical Chemistry Molecular Biology Spectroscopy Catalysis Computer Science Applications
Zdroj:	International Journal of Molecular Sciences; Volume 24; Issue 10; Pages: 8541
ISSN:	1422-0067
DOI:	10.3390/ijms24108541
Popis:	Herein we report a comprehensive laboratory synthesis of a series of energetic azidonitrate derivatives (ANDP, SMX, AMDNNM, NIBTN, NPN, 2-nitro-1,3-dinitro-oxypropane) starting from the readily available nitroisobutylglycerol. This simple protocol allows obtaining the high-energy additives from the available precursor in yields higher than those reported using safe and simple operations not presented in previous works. A detailed characterization of the physical, chemical, and energetic properties including impact sensitivity and thermal behavior of these species was performed for the systematic evaluation and comparison of the corresponding class of energetic compounds.
Databáze:	OpenAIRE
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