A New Synthetic Route for the Preparation of 1,10-Phenanthroline Derivatives

Autor:	Fettah Ajamaa, Allan Ekouaga, Jean-François Nierengarten, Omar Moudam, Uwe Hahn, Richard Welter, Hind Mamlouk, Michel Holler
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Benzyl bromide Chemistry Phenanthroline Organic Chemistry Organic chemistry Reactivity (chemistry) General Medicine Physical and Theoretical Chemistry Organolithium reagent Combinatorial chemistry
Zdroj:	European Journal of Organic Chemistry. 2007:417-419
ISSN:	1099-0690 1434-193X
DOI:	10.1002/ejoc.200600772
Popis:	The intermediate resulting from the addition of an organolithium reagent to 1,10-phenanthroline has been quenched with benzyl bromide. The resulting protected dihydrophenanthroline intermediate is thus stabilized and can be used for further chemical transformations. This strategy allows to modify the reactivity of the phenanthroline backbone and offers a unique opportunity to perform chemical modifications that would not be possible when starting from 1,10-phenanthroline. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Databáze:	OpenAIRE
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