Cotemplating synthesis of a rare borate Ni(en)3·Hen·[B9O13(OH)4]·H2O with a chiral polyanonic chain constructed from two different clusters

Autor: Chun-Yang Pan, Li‐Juan Zhong, Yuan-Zhang Luo, Feng-Hua Zhao, Da-Guang Li
Rok vydání: 2014
Předmět:
Zdroj: Inorganic chemistry. 54(2)
ISSN: 1520-510X
Popis: Ni(en)3·Hen·[B9O13(OH)4]·H2O was prepared under the cotemplating effect of [Ni(en)3](2+) and Hen(+). It was the first example of a cotemplated borate with an unusual chiral polyanionic chain, which was constructed from [B5O8(OH)2] and [B4O7(OH)2] clusters.
Databáze: OpenAIRE