Possibility of Emergence of Chiral Magnetic Soliton in Hexagonal Metal Formate [NH4][M(HCOO)3] with M2+ = Mn, Fe, Co, and Ni and KCo(HCOO)3
Autor: | L. M. Volkova, D. V. Marinin |
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Jazyk: | angličtina |
Rok vydání: | 2015 |
Předmět: |
Materials science
FOS: Physical sciences 02 engineering and technology Crystal structure 01 natural sciences Metal chemistry.chemical_compound Condensed Matter - Strongly Correlated Electrons Metastability 0103 physical sciences Antiferromagnetism Formate 010306 general physics Condensed Matter - Materials Science Strongly Correlated Electrons (cond-mat.str-el) Hexagonal crystal system Materials Science (cond-mat.mtrl-sci) 021001 nanoscience & nanotechnology Condensed Matter Physics Polarization (waves) Electronic Optical and Magnetic Materials Crystallography chemistry visual_art visual_art.visual_art_medium Soliton 0210 nano-technology |
Popis: | Search of chiral magnetic solitons on the basis of the data on the crystal structure is important from both fundamental and technological points of view. Potential chiral magnetic solitons - hexagonal metal formates [NH4][M(HCOO)3] with M2+ = Mn, Fe, Co, and Ni and KCo(HCOO)3 containing dominating left-handed chiral antiferromagnetic helices that compete with interhelix interactions have been identified. The sign and strength of magnetic interactions not only between nearest neighbors, but also for longer-range neighbors in the metal formates have been calculated on the basis of structural data. Magnetic structures of these compounds are similar to that of the chiral magnetic soliton Cr1/3NbS2. The interrelation between chiral polarization of crystalline and magnetic structures in the metastable polymorph KCo(HCOO)3 has been demonstrated. 14 pages, 10 figures,3 tables, published version in J Supercond Nov Magn 2016 |
Databáze: | OpenAIRE |
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